| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328016 | Journal of Organometallic Chemistry | 2008 | 5 Pages |
Abstract
A reaction of Me3Al with 2,2′-methylene-p-chloro-bisphenol in Et2O yielded Me5Al3[OC6H3(Cl)CH2C6H3(Cl)O]2 (1). Compound 1 reacted with 2,2′-di(hydroxymethyl)biphenyl to form Me3Al3[OC6H3(Cl)CH2C6H3(Cl)O](OCH2C12H8CH2O)2 (2) bearing two kinds of diolate ligands. Compound 2 was structurally characterised.
Graphical abstractMethyl aluminium-(2,2′-methylene-p-chloro-bisphenoxide), Me5Al3[OC6H3(Cl)CH2C6H3(Cl)O]2, (1) reacted with 2,2′-di(hydroxymethyl)biphenyl to form Me3Al3[OC6H3(Cl)CH2C6H3(Cl)O](OCH2C12H8CH2O)2 (2) bearing two kinds of diolate ligands.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Wanda Ziemkowska, Magdalena Metelska, Przemysław Kruk, Romana Anulewicz-Ostrowska,