| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328022 | Journal of Organometallic Chemistry | 2008 | 8 Pages |
The iminophosphorane Ph2MePNPh (1) reacts with Pd(OAc)2 to give the orthopalladated [Pd(μ-Cl){C6H4(PPh(Me)NPh-κ-C,N)-2}]2 (2) as the racemic mixture, which reacts with Tl(acac) to give [Pd(acac){C6H4(PPh(Me)NPh-κ-C,N)-2}] (3). The X-ray structure of (3) has been determined by diffraction methods. The phosphorus ylide Ph2MePCHC(O)Ph (5) reacts with Pd(OAc)2 to give the dinuclear [Pd(μ-Cl){C6H4(PPh(Me)CHC(O)Ph-κ-C,C)-2}]2 (6) as a mixture of isomers. Complex (6) reacts with Tl(acac), PPh3 or AgClO4/dppe giving the mononuclear derivatives [Pd(acac){C6H4(PPh(Me)CHC(O)Ph-κ-C,C)-2}] (7), [PdCl{C6H4(PPh(Me)CHC(O)Ph-κ-C,C)-2}PPh3] (8) and [Pd{C6H4(PPh(Me)CHC(O)Ph-κ-C,C)-2}(dppe–P,P′)](ClO4) (9), as mixtures of stereoisomers with high diastereomeric excess.
Graphical abstractThe compounds Ph2MePNPh (1) and Ph2MePCHC(O)Ph (5) react with Pd(OAc)2 to give the orthopalladated [Pd(μ-Cl){C6H4(PPh(Me)NPh-κ-C,N)-2}]2 (2), as the racemic mixture, and [Pd(μ-Cl){C6H4(PPh(Me)CHC(O)Ph-κ-C,C)-2}]2 (6), as a mixture of diastereoisomers with high d.e. The reactivity of 2 and 6 has been examined and the X-ray crystal structure of [Pd(acac){C6H4(PPh(Me)NPh-κ-C,N)-2}] (3) has been determined.Figure optionsDownload full-size imageDownload as PowerPoint slide
