| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328120 | Journal of Organometallic Chemistry | 2007 | 4 Pages |
Abstract
The synthesis, characterization and catalytic activity in ethylene polymerization of novel mononuclear vanadium complexes bearing N∧N∧N-tridentate (pyrazolyl-pyridine) ligands are described. With AlEtCl2 as co-catalyst, complexes 1 and 2 produce single-site catalysts that polymerized ethylene affording high density polyethylene with fairly narrow molecular weight distribution.
Graphical abstractThe novel mononuclear vanadium complexes (1 and 2) bearing N∧N∧N-tridentate (pyrazolyl-pyridine) ligands when activated with AlEtCl2 produce single-site catalysts that polymerize ethylene affording high density polyethylene with fairly narrow molecular weight distribution.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Hanna S. Abbo, Selwyn F. Mapolie, James Darkwa, Salam J.J. Titinchi,