Synthesis, characterization and luminescence study of dimethyl[2-(arylmethyleneimino)phenolato]gallium complexes: Crystal structure of dimethyl[N-(4-N,N′-dimethylamino) phenylmethyleneiminophenolato]gallium

Three dimethylgallium complexes of type Me2GaL [L = 2-methoxylphenylmethyleneiminophenolato (1), N-(4-N,N′-dimethylamino)phenylmethyleneiminophenolato (2), N-(2-naphthyl)methyleneiminophenolato (3)] have been synthesized by the reaction of trimethylgallium with appropriate N-arylmethyleneiminophenol. The complexes obtained have been characterized by elemental analysis, 1H, 13C{1H} NMR, IR and mass spectroscopy, respectively. The solid structure of 2 has been determined by X-ray single crystal analysis. The gallium atom was bonded by an oxygen atom and coordinated by an imine nitrogen atom forming one five-membered ring. The stable dimmer was formed by the coordination of bridging oxygen atom of phenolate to another gallium atom. The photoluminescence of complexes 1–3 were studied. The maximum emission wavelengths of 1–3 are between 305 and 320 nm upon radiation by UV light. The electroluminescent properties of diodes using 1–3 as emitting material were measured. The blue/green electroluminescence has been observed.

Graphical abstractThree dimethylgallium complexes of type Me2GaL [(L = 2-methoxylphenylmethyleneiminop henolato (1), N-(4-N,N′-dimethyl amino)phenylmethyleneiminophenolato (2), N-(2-naphthyl)methyleneiminophenolato (3), have been synthesized. The solid structure of 2 has been determined by X-ray analysis. The electroluminescent properties of 1 – 3 have been measured. The maximum emission wavelengths are in the range of 305 and 320 nm.Figure optionsDownload full-size imageDownload as PowerPoint slide