| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328184 | Journal of Organometallic Chemistry | 2007 | 5 Pages |
Abstract
This paper reports facile preparation of half-sandwich trihydrido complexes of ruthenium based on the reactions of the readily available precursors [Cp(R3P)Ru(NCCH3)2][PF6] with LiAlH4. The target complexes were characterized by spectroscopic methods and X-ray structure analysis of Cp(PhPr2iP)RuH3.
Graphical abstractHalf-sandwich trihydrido complexes of ruthenium can be easily prepared by the reaction of [Cp(R3P)Ru(NCCH3)2]+[EFn]− (EFn = BF4,PF6]) with LiAlH4.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Alexandr L. Osipov, Dmitry V. Gutsulyak, Lyudmila G. Kuzmina, Judith A.K. Howard, Dmitry A. Lemenovskii, Georg Süss-Fink, Georgii I. Nikonov,