Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1328201 | Journal of Organometallic Chemistry | 2007 | 5 Pages |
Abstract
The reaction of CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(AlMe2)3 with ClSnMe3 and MeO3SCF3 affords the species CpTi(μ2-Cl)(μ2-NPi-Pr3)(μ4-C)(μ2-Cl)(AlMe)(AlMe2)21 and CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(μ2-O3SCF3)(AlMe)(AlMe2)22, respectively. Both 1 and 2 have been structurally characterized.
Graphical abstractTOC EntryReaction of CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(AlMe2)3 with ClSnMe3 and MeO3SCF3 afford the species [CpTi(μ2-Cl)(μ2-NPi-Pr3)(μ4-C)(μ2-Cl)(AlMe)(AlMe2)2] 1 and [CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(μ2-O3SCF3)(AlMe)(AlMe2)2] 2, respectively.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Todd W. Graham, Christopher Ong, Pingrong Wei, Douglas W. Stephan,