Carbohydrate-containing N-heterocyclic carbene complexes

Novel carbohydrate bearing imidazolium salts have been synthesized and used for the in situ generation of the corresponding N-heterocyclic carbenes. These compounds were successfully used as catalysts of the conjugate umpolung of cinnamaldehyde to form γ-butyrolactones. In addition, silver and palladium complexes of these N-heterocyclic carbenes were synthesized and structurally characterized.

Graphical abstractNovel carbohydrate bearing imidazolium salts have been synthesized and used for the in situ generation of the corresponding N-heterocyclic carbenes 1. These compounds were successfully used as catalysts of the conjugate umpolung of cinnamaldehyde to form γ-butyrolactones. In addition, silver and palladium complexes of these N-heterocyclic carbenes were synthesized and structurally characterized.Figure optionsDownload full-size imageDownload as PowerPoint slide