| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328234 | Journal of Organometallic Chemistry | 2007 | 8 Pages |
Abstract
A unique Ï-conjugative six-center-six-electron bonding network was revealed in the doubly acetylide-bridged binuclear group 4 metallocene complexes. The coplanar multi-center bonding interaction between the metal centers and acetylide ligands not only significantly stabilizes the doubly acetylide-bridged complexes but also lowers the isomerization barrier.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Shuqiang Niu, Agnes Derecskei-Kovacs, Michael B. Hall,