Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1328280 | Journal of Organometallic Chemistry | 2007 | 4 Pages |
Abstract
A stannylene acetal, in the presence of CsF, is able to cleave both aromatic and aliphatic acetates rapidly and efficiently under room temperature. Control experiments indicate that both the stannylene acetal and CsF are required and play significant roles in the deacetylation process. Thus, it is likely that the tin-based alkoxide anion generated by a stannylene acetal and CsF is responsible for deacetylation.
Graphical abstractA combination of cyclic dialkyltin alkoxide with CsF can deacetylate acetates under very mild condition, and a likely deacetylation mechanism is proposed.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Weiying Lin, Lingliang long, Daiwei Peng, Cancheng Guo,