Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1328328 | Journal of Organometallic Chemistry | 2007 | 7 Pages |
Allenes react with Grignard reagents and chlorosilanes in the presence of a palladium catalyst giving rise to carbosilylated products bearing carbon groups from Grignard reagents at the central carbon and silyl groups at the terminal carbon. When alkyl halides were used instead of chlorosilanes, the corresponding alkylated products were obtained.
Graphical abstractAllenes react with Grignard reagents and chlorosilanes in the presence of a palladium catalyst giving rise to carbosilylated products bearing carbon groups from Grignard reagents at the central carbon and silyl groups at the terminal carbon. When alkyl halides were used instead of chlorosilanes, the corresponding alkylated products were obtained.Figure optionsDownload full-size imageDownload as PowerPoint slide