| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328330 | Journal of Organometallic Chemistry | 2007 | 7 Pages |
Abstract
The complex cis-Pt(Ph3Ge)2(PMe2Ph)2 underwent smooth isomerization to give the trans-isomer at room temperature via an associative five-coordinated intermediate. Thermodyamic parameters and activation energy for the cis to trans isomerization were obtained. Heating of trans-Pt(Ph3Ge)2(PMe2Ph)2 at 50 °C produced trans-PtPh(Ph3Ge)(PMe2Ph)2 followed by the formation of trans-PtPh2(PMe2Ph)2, Pt(PMe2Ph)4, and Ph4Ge finally.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Kunio Mochida, Takashi Fukushima, Michiko Suzuki, Wakako Hatanaka, Mariko Takayama, Yoko Usui, Masato Nanjo, Kuniyoshi Akasaka, Takako Kudo, Sanshiro Komiya,