Article ID Journal Published Year Pages File Type
1328345 Journal of Organometallic Chemistry 2007 6 Pages PDF
Abstract
In the presence of Et3B-dry air, dibutylchlorogermane (Bu2GeClH) reacted smoothly with alkenes at room temperature to give hydrogermylation products in high yields. This homolytic hydrogermylation was applicable to various alkenes including electron-deficient, electron-rich, and internal alkenes. Tributylgermane (Bu3GeH) showed much lower reactivity than Bu2GeClH.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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