Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1328345 | Journal of Organometallic Chemistry | 2007 | 6 Pages |
Abstract
In the presence of Et3B-dry air, dibutylchlorogermane (Bu2GeClH) reacted smoothly with alkenes at room temperature to give hydrogermylation products in high yields. This homolytic hydrogermylation was applicable to various alkenes including electron-deficient, electron-rich, and internal alkenes. Tributylgermane (Bu3GeH) showed much lower reactivity than Bu2GeClH.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Katsukiyo Miura, Kazunori Ootsuka, Akira Hosomi,