| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328350 | Journal of Organometallic Chemistry | 2007 | 4 Pages |
Abstract
A catalytic asymmetric aldol reaction of alkenyl trichloroacetates with aldehydes was achieved using dibutyltin dimethoxide and BINAP · silver(I) complex as catalysts in a mixed solvent consisting of THF and MeOH. Various optically active β-hydroxy ketones were diastereoselectively obtained with good enantioselectivity up to 92% ee.
Related Topics
Physical Sciences and Engineering
Chemistry
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Authors
Akira Yanagisawa, Toshikazu Ichikawa, Takayoshi Arai,