| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328387 | Journal of Organometallic Chemistry | 2006 | 6 Pages |
Abstract
An easy approach to Fischer (NHC)carbene complexes of rhodium(I) 3 from methoxy- and aminocarbene complexes of chromium 1 and (NHC)(cod)RhCl (2) is described. The process involves the transfer of the carbene unit and a CO ligand from chromium to rhodium. The X-ray analysis is provided for 3d and the preliminary results on their thermal stability and reactivity toward alkynes and allenes are also reported.
Graphical abstractA new type of metal carbene complex of group 9, specifically NHC/Fischer biscarbene complexes of rhodium(I), is synthesized and fully characterized. Preliminary results on their thermal stability and reactivity toward alkynes and allenes are also reported.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
José Barluenga, Rubén Vicente, Luis A. López, Miguel Tomás,