Article ID Journal Published Year Pages File Type
1328410 Journal of Organometallic Chemistry 2006 7 Pages PDF
Abstract

Several gallium and indium dithiocarboxylate complexes of the type [MenM(S2CR)3−n] (M = Ga, In; n = 0, 1, 2; R = phenyl (Ph), p-tolyl (tol), mesityl (Mes)) have been synthesized. These complexes were characterized by elemental analysis, IR, UV–vis and NMR (1H,13C{1H}) spectroscopy. Structure of [MeGa(S2Ctol)2] was established by X-ray crystallography. The gallium atom adopts a distorted five coordinate geometry which is intermediate between trigonal bipyramidal and square pyramidal configurations. The complex [Me2InS2Ctol] underwent a two-step thermal decomposition leading to the formation of tetragonal β-In2S3.

Graphical abstractSeveral gallium and indium dithiocarboxylate complexes of the type [MenM(S2CR)3−n] (M = Ga, In; n = 0, 1, 2; R = phenyl (Ph), p-tolyl (tol), mesityl (Mes)) have been synthesized and characterized by spectroscopic methods. Structure of [MeGa(S2Ctol)2] has been established by X–ray crystallography. The complex [Me2InS2Ctol] underwent a two-step thermal decomposition leading to the formation of tetragonal β-In2S3.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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