Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1328412 | Journal of Organometallic Chemistry | 2006 | 5 Pages |
Abstract
Indium(I) bromide promotes the reaction of α,α-dichloroketones with aldehydes to produce (E)-α,β-unsaturated ketones, exclusively. The transformation occurs via two sequential reactions, an aldol-type coupling between the two carbonylic reagents followed by an elimination process.
Graphical abstractIndium(I) bromide promotes the reaction of α,α-dichloroketones with aldehydes to produce (E)-α,β-unsaturated ketones, exclusively. The transformation occurs via two sequential reactions, an aldol-type coupling between the two carbonylic reagents followed by an elimination process.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Clovis Peppe, Rafael Pavão das Chagas,