| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328466 | Journal of Organometallic Chemistry | 2006 | 5 Pages |
Abstract
Addition of ethynylferrocene to nido-1,2-(CpâRuH)2B3H7 (1) at ambient temperature leads to nido-1,2-(CpâRu)2(1,5-μ-C{Fc}Me)B3H7 (2, 3) and closo-4-Fc-1,2-(CpâRuH)2-4,6-C2B2H3 (4). Compounds 2 and 3 represent a pair of geometric isomers with a nido structure where the regiochemistry of the alkyne reduction conforms to the Markovnikoff rule, while 4 is an octahedral structure where the inserted alkyne is on an open face of the closo cluster.
Related Topics
Physical Sciences and Engineering
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Inorganic Chemistry
Authors
Hong Yan, Bruce C. Noll, Thomas P. Fehlner,