| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328498 | Journal of Organometallic Chemistry | 2006 | 9 Pages |
The [Mn(CO)4−x(L){Ph2P(Se)NP(Se)Ph2-κ2Se}] complexes, where x = 1 for L = PPh3 and PMePh2, and x = 2 for L = Ph2PCH2CH2PPh2 (diphos), were synthesized by two routes. The complexes were characterized by IR, mass spectrometry (FAB+), NMR (1H, 13C, 31P, 77Se) spectroscopy and/or single crystal X-ray diffraction. The X-ray diffraction analysis for [Mn(CO)3PMePh2{Ph2P(Se)NP(Se)Ph2-κ2Se}] showed that the unit cell contains two independent mononuclear molecules with different MnSePNPSe rings’ conformations.
Graphical abstractTwo routes for the preparation of manganacycles [Mn(CO)4−x(L){Ph2P(Se)NP(Se)Ph2-κ2Se}], where x = 1 for L = PPh3 and PMePh2, and x = 2 for L = Ph2PCH2CH2PPh2 (diphos), are reported. The new complexes were characterized either in solution or in the solid state.Figure optionsDownload full-size imageDownload as PowerPoint slide
