| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328502 | Journal of Organometallic Chemistry | 2006 | 9 Pages |
Abstract
Triple-decker complexes with a bridging borole ligand (C4H4BPh)Rh(μ-C4H4BPh)ML (ML = RuCp, 2a; RuCp∗, 2b; FeCp∗, 3; Co(C4Me4), 4; Ir(cod), 5) were synthesized by stacking reactions of [Rh(C4H4BPh)2]− (1) with cationic [ML]+ fragments. The structures of 2a,b and (C4H4BPh)Rh(μ-C4H4BPh)Rh(C4H4BPh) (6) were determined by X-ray diffraction.
Graphical abstractNew triple-decker complexes (C4H4BPh)Rh(μ-C4H4BPh)ML with a bridging borole ligand were synthesized by stacking reactions of anion [(C4H4BPh)2Rh]− with cationic fragments [ML]+. Structures of three compounds were determined by X-ray diffraction study.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dmitry V. Muratov, Pavel V. Petrovskii, Zoya A. Starikova, Gerhard E. Herberich, Alexander R. Kudinov,