| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328507 | Journal of Organometallic Chemistry | 2006 | 5 Pages |
Abstract
Photolysis of W(CO)6 or W(CO)5[P(OCH3)3] in the presence of acryloylferrocene in n-hexane solution yields pentacarbonyl(η2-acryloylferrocene)tungsten(0) or cis-W(CO)4[P(OCH3)3](η2-acryloylferrocene), respectively, as the only photo-substitution product. Both η2-acryloylferrocene complexes could be isolated and characterized by MS, IR and NMR spectroscopy. Both complexes are found to be labile in solution towards decomposition to the parent carbonyltungsten(0) and free acryloylferrocene.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dilek AyÅe BoÄa, Saim Ãzkar,