Article ID Journal Published Year Pages File Type
1328539 Journal of Organometallic Chemistry 2006 7 Pages PDF
Abstract
Treatment of titanium phosphinoamide, (Ph2PNtBu)2TiCl2 (1), with [Cp∗RuCl]4 afforded Cp∗Ru(μ-Cl)(Ph2PNtBu)2TiO (3) through Cp∗Ru(μ-Cl)(Ph2PNtBu)2TiCl2 (2) as an intermediate. The molecular structure of 3 indicated the existence of intramolecular donor-acceptor interaction between the lone pair electrons of μ-Cl atom and the Lewis acidic titanium center.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Titanium(IV) phosphinoamide as a unique bidentate ligand for late transition metals II: TiRu heterobimetallics bearing a bridging chlorine atom
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