Article ID Journal Published Year Pages File Type
1328608 Journal of Organometallic Chemistry 2006 7 Pages PDF
Abstract
Reaction of the heteronuclear cluster Cp∗IrOs3(μ-H)4(CO)9 with alkynes is activated by excess amine to afford the butterfly clusters Cp∗IrOs3(CO)9(RCCR′); hinge-apex isomers are formed. In the case of PhCCH, another cluster Cp∗IrOs3(CO)9(CCHPh)2, which contained two alkenyl moieties was also isolated.
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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Reaction of the heteronuclear cluster Cp*IrOs3(μ-H)4(CO)9 with alkynes: An unusual case of amine activation
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