| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1328613 | Journal of Organometallic Chemistry | 2006 | 4 Pages |
Abstract
Deprotonated 1,3-bis(3-acetylphenyl)triazene reacts with Hg(CH3COO)2 and pyridine to give tectonic [HgII(RC6H4NNNC6H4R)2Py] [R = CH3C(O)]. The tectons are linked to pairs as centrosymmetric dimers through reciprocal metal-η2-arene Ï-interactions. The dimeric units assemble a supramolecular bidimensional lattice through non classical C-Hâ¯(O)CCH3 bonding.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Polymeric bidimensional self-assembling of [HgII(RC6H4NNNC6H4R)2Py] (R = m-acetyl) through metal-η2,η2-arene Ï-interactions and non classical C-Hâ¯O bonding: Synthesis and X-ray characterization of a bis diaryl symmetric-substituted triazenide compl](/preview/png/1328613.png "First Page Preview: Polymeric bidimensional self-assembling of [HgII(RC6H4NNNC6H4R)2Py] (R = m-acetyl) through metal-η2,η2-arene Ï-interactions and non classical C-Hâ¯O bonding: Synthesis and X-ray characterization of a bis diaryl symmetric-substituted triazenide compl")
Authors
Manfredo Hörner, Gelson Manzoni de Oliveira, Eduardo Giuliani Koehler, Lorenzo do CantoVisentin,