Synthesis and electrochemical studies of organometallic cobalt(III) complexes with substituted benzonitrile chromophores: NMR spectroscopic data as a probe on the second-order non-linear optical properties

The family of organometallic Co(III) benzonitrile derivatives of general formula [CoCp(dppe)(p-NCR)][PF6]2 (R = C6H4NMe2, C6H4NH2, C6H4OMe, C6H4C6H5, C6H5, C6H4C6H4NO2, and C6H4NO2) have been synthesized. Spectroscopic and electrochemical data were analyzed in order to evaluate the extent of electronic coupling between the organometallic fragment and the nitrile ligands. An attempt of correlation between NMR spectroscopic data and the second-order non-linear optical properties is presented, based on this work and available published data for related η5-monocyclopentadienyliron, ruthenium and nickel complexes.

Graphical abstractA family of η5-cyclopentadienylcobalt complexes with p-substituted benzonitrile chromophores was prepared, characterized and studied by cyclic voltammetry. A correlation between NMR spectroscopic data and the second-order non-linear optical properties is presented, based on this work and on available published data for related complexes.Figure optionsDownload full-size imageDownload as PowerPoint slide