Intercalation chemistry of zirconium 4-sulfophenylphosphonate

•Zirconium 4-sulfophenylphosphonate was examined as a host material in intercalation chemistry.•A wide range of nitrogen-containing organic compounds were intercalated.•Possible arrangement of the intercalated species is described.

Zirconium 4-sulfophenylphosphonate is a layered material which can be employed as a host for the intercalation reactions with basic molecules. A wide range of organic compounds were chosen to represent intercalation ability of zirconium 4-sulfophenylphosphonate. These were a series of alkylamines from methylamine to dodecylamine, 1,4-phenylenediamine, p-toluidine, 1,8-diaminonaphthalene, 1-aminopyrene, imidazole, pyridine, 4,4′-bipyridine, poly(ethylene imine), and a series of amino acids from glycine to 6-aminocaproic acid. The prepared compounds were characterized by powder X-ray diffraction, thermogravimetry analysis and IR spectroscopy and probable arrangement of the guest molecules in the interlayer space of the host is proposed based on the interlayer distance of the prepared intercalates and amount of the intercalated guest molecules.

Graphical abstractNitrogen-containing organic compounds can be intercalated into the interlayer space of zirconium 4-sulfophenylphosphonate.Figure optionsDownload full-size imageDownload as PowerPoint slide