Article ID Journal Published Year Pages File Type
1329217 Journal of Solid State Chemistry 2009 4 Pages PDF
Abstract

Reactions of different metal salts with 3-pyridin-4-yl-benzoic acid (3,4-Hpybz) under ambient condition afford a series of 3-D metal-organic frameworks with two new types of (3,6)-connected net topologies. In the isomorphic complexes [M2(μ-H2O)(3,4-pybz)4]n (MII=MnII for 1, ZnII for 2, or CdII for 3), the octahedral metal nodes are extended by the 3-connected pybz tectons to constitute 3-D arrays with the Schläfli symbol of (3.4.5)(32.44.55.62.72), whereas [Pb(3,4-pybz)2]n (4) shows a completely different 3-D (42.6)2(44.62.89) framework, which represents a subnet of the (4,8)-connected fluorite lattice.

Graphical abstractThis work presents a series of 3-D metal-organic frameworks with 3-pyridin-4-yl-benzoate, which display new (3,6)-connected net topologies of (3.4.5)(32.44.55.62.72) for MnII/ZnII/CdII and (42.6)2(44.62.89) for PbII species.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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