| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1329225 | Journal of Solid State Chemistry | 2009 | 7 Pages |
A novel series of luminescent mesoporous organic–inorganic hybrid materials has been prepared by linking Eu3+ complexes to the functionalized ordered mesoporous SBA-15 which was synthesis by a co-condensation process of 1,3-diphenyl-1,3-propanepione (DBM) modified by the coupling agent 3-(triethoxysilyl)-propyl isocyanate (TEPIC), tetraethoxysilane (TEOS), Pluronic P123 surfactant as a template. It was demonstrated that the efficient intramolecular energy transfer in the mesoporous material Eu(DBMSi-SBA-15)3phen mainly occurred between the modified DBM (named as DBM-Si) and the central Eu3+ ion. So the Eu(DBMSi-SBA-15)3phen showed characteristic emission of Eu3+ ion under UV irradiation with higher luminescence quantum efficiency. Moreover, the mesoporous hybrid materials exhibited excellent thermal stability as the lanthanide complex was covalently bonded to the mesoporous matrix.
Graphical abstractA novel organic–inorganic mesoporous luminescent hybrid materials is prepared by linking the binary and ternary Eu3+ complexes to the functionalized ordered mesoporous SBA-15 with the modified 1,3-diphenyl-1,3-propanepione (DBM) via a co-condensation process of tetraethoxysilane (TEOS) in the presence of Pluronic P123 surfactant as a template.Figure optionsDownload full-size imageDownload as PowerPoint slide
