| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1329604 | Journal of Solid State Chemistry | 2015 | 7 Pages |
•The first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3 is reported.•Hydrothermal conditions (240 °C, 3d) were used for the synthesis of K3Na[B6O9(OH)3]NO3.•Borate Sechserrings are interconnected through hydrogen-bonding.
The first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3 was synthesized under hydrothermal conditions from Na2B4O7·10H2O and K2B4O7·4H2O using KNO3 as a nitrate source. The compound crystallizes in the space group Pnnm (no. 58) with the lattice parameters a=1320.8(3), b=910.7(2), and c=1232.5(3) pm (Z=4). Isolated Sechserrings formed by BO4 and BO3 groups are linked through hydrogen bridges to form a three-dimensional network.
Graphical abstractThe first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3 was synthesized under hydrothermal conditions from Na2B4O7·10H2O and K2B4O7·4H2O using KNO3 as a nitrate source.Figure optionsDownload full-size imageDownload as PowerPoint slide
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