Article ID Journal Published Year Pages File Type
1329980 Journal of Solid State Chemistry 2013 5 Pages PDF
Abstract

The structure and elementary physical properties of a new intermetallic compound, β-HfCuGeβ-HfCuGe, are reported. β-HfCuGeβ-HfCuGe has a tetragonal structure (space group I4/mmm) with lattice constants of a=3.7634(11)Å and c=13.499(4) Å. The structure, which consists of double layers of Hf stacked with edge-sharing CuGe4 squares, is not typical for intermetallic compounds and appears to be a new structure type. The compound is a weak paramagnet and a normal metal down to 0.4 K.

Graphical abstractCrystal structure of β-HfCuGeβ-HfCuGe (right) and the coordination of the different atoms in ββ-HfCuGe (left).Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Layered intermetallic compound. ► BCC Hf layers and square planar CuGe network. ► Metallic conductor and paramagnetic.

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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