Color Point Tuning by Partial Ba2+ Substitution of Ca2+ in (Ca1−xBax)3(PO4)2 Phosphor for White Light Emitting Diodes

A potential phosphor (Ca1−xBax)3(PO4)2:Eu2+ was synthesized by a solid-state reaction. X-ray diffraction (XRD) analysis confirmed the formation of (Ca1−xBax)3(PO4)2 crystal phase. With the Ba2+ content increasing, the bandgap of (Ca1−xBax)3(PO4)2 increases from 5.5 to 5.9 eV, and the crystal field splitting between the two lowest Eu2+ 5d levels is enhanced from 6085 to 6808 cm−1 in (Ca1−xBax)3(PO4)2. As a result, the emission peak of (Ca1−xBax)3(PO4)2: Eu2+ shifts from 447 to 550 nm, which means that the emission color alters from blue to yellow. The redshift of the emission band of (Ca1−xBax)3(PO4)2:Eu2+ was explained based on crystal field strength, covalence, Stokes shift. The results revealed that partial substitution of Ca2+ by Ba2+ ions was therefore a much considerable way to shift the color point of LEDs.

Graphical abstractWith the Ba2+ content increasing, the emission peak of (Ca1−xBax)3(PO4)2: Eu2+ shifts from 447 to 550 nm, and the chromaticity coordinates shifted from (0.2037, 0.3026) to (0.3295, 0.4638).Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► (Ca1−xBax)3(PO4)2:Eu2+ phosphor could be effectively excited by UV chips (360–430 nm). ► the emission wavelength can be tuned in the range of 447–550 nm with different Ba2+content. ► With the Ba2+ content increasing, the bandgap of (Ca1−xBax)3(PO4)2 broadens from 5.5 to 5.9 eV.