Study of the pseudo-ternary Ag2SAs2S3HgI2 vitreous system

Chalcogenide alloys in the Ag2SAs2S3HgI2 pseudo-ternary system were synthesized and their vitreous nature was verified by X-ray diffraction. The glass transition and crystallization temperatures (Tg and Tc), the density (d), and the total electrical conductivity (σ) were measured for all samples of three series, A, B, and C corresponding to (Ag2S)50−x/2(As2S3)50−x/2(HgI2)x, (Ag2S)y(As2S3)80−y(HgI2)20 and (Ag2S)z(As2S3)50(HgI2)50−z, respectively. The maximum of Tg was approximately 160 °C for glasses with low HgI2 content whereas the maximum of density (5.75 g cm−3) was obtained for the sample in the B-series with the highest Ag2S concentration (z=60 mol%). This composition also possesses the highest conductivity at 298 K (σ298 K≈10−3 S cm−1). Unexpectedly the conductivity of the A-series samples was observed to decrease as a function of the Ag2S content. The far-infrared transmission in the 100–600 cm−1 window range (3.3–18.2 THz, 100–16.6 μm) was also given for a few glass compositions highlighting the strong influence of the HgI2 content.

Graphical abstractGlass-forming region of the pseudo-ternary Ag2SAs2S3HgI2 system. Emphasis on the evolution of conductivity properties, glass transition temperature, and far-infrared transmission of the A-series glasses (Ag2S)50−x/2 (As2S3)50−x/2 (HgI2)x is shown.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Studies of three glass series in the pseudo-ternary Ag2SAs2S3HgI2 system. ► Investigation of some macroscopic properties of the Ag2SAs2S3HgI2 glasses. ► HgI2 contribution in the far-infrared transmission of the pseudo-ternary Ag2SAs2S3HgI2 glasses. ► Characterization of the total conductivity of Ag2SAs2S3HgI2 glasses.