| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1330254 | Journal of Solid State Chemistry | 2012 | 7 Pages |
While HRTEM is the well-established method to characterize the structure of dodecagonal tantalum (vanadium) telluride quasicrystals and their periodic approximants, phase-contrast imaging performed on an aberration-corrected scanning transmission electron microscope (STEM) represents a favorable alternative. The (Ta,V)151Te74 clusters, the basic structural unit in all these phases, can be visualized with high resolution. A dependence of the image contrast on defocus and specimen thickness has been observed. In thin areas, the projected crystal potential is basically imaged with either dark or bright contrast at two defocus values close to Scherzer defocus as confirmed by image simulations utilizing the principle of reciprocity. Models for square–triangle tilings describing the arrangement of the basic clusters can be derived from such images.
Graphical abstractPC-STEM image of a (Ta,V)151Te74 cluster.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Cs-corrected STEM is applied for the characterization of dodecagonal quasicrystals. ► The projected potential of the structure is mirrored in the images. ► Phase-contrast STEM imaging depends on defocus and thickness. ► For simulations of phase-contrast STEM images, the reciprocity theorem is applicable.
