Synthesis and properties of a few 1-D cobaltous fumarates

Metal fumarates are often studied in the context of metal organic framework solids. Preparation, structure and properties of three cobalt(II) fumarates, viz. [Co(fum)(H2O)4]·H2O 1, [Co(fum)(py)2(H2O)2] 2, and [Co(fum)(4-CNpy)2(H2O)2] 3 (fum=fumarate, py=pyridine, 4-CNpy=4-cyanopyridine) are described. All three are chain polymers involving bridging fumarato ligands between each pair of octahedral Co(II) centres, but while the first one is zigzag in structure, the latter two are linear. Indexed powder X-ray diffraction patterns, solid state electronic spectra and magnetic properties of the species are reported. Thermal decomposition behaviour of the compounds suggests that they may be suitable as precursors to make Co3O4 via pyrolysis below 600 °C.

Graphical abstractStructure and properties of three chain-polymeric cobalt(II) fumarates are described .Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Three fumarate bridged 1-D coordination polymers of cobalt(II) are reported. ► While Co(II) fumarate pentahydrate is zigzag, the species having both pyridine and water as co-ligands are linear in structure. ► Prominent lines in the powder X-ray diffraction patterns have been indexed. ► Thermal decomposition of the species yields Co3O4 as the final product.