| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1330519 | Journal of Solid State Chemistry | 2011 | 5 Pages |
Single crystals of the novel compound BaSn6Co6O19 with maximum width 1 mm and thickness around 0.05 mm were grown from a barium chloride flux. The composition was determined from refinements of single crystal X-ray diffraction data and microprobe analysis. BaSn6Co6O19 crystallizes in the magnetoplumbite type structure (hexagonal, space group P63/mmc, a=6.0940(1) Å, c=23.9633(5) Å, V=770.69 Å3, Z=2). A significant disorder is generated by random occupation of two octahedrally coordinated crystallographic sites with Co2+ and Sn4+ ions, while further sites are exclusively occupied by either Co2+ (tetrahedrally coordinated) or Sn4+ (octahedrally coordinated). One site with mixed occupation realizes the topology of a kagome net. The temperature dependence of the magnetic susceptibility for a single crystal BaSn6Co6O19 reveals a low temperature antiferromagnetic order at TN=14 K. A relatively large value of frustration factor f//=|ΘW//|/TN≈26 and f⊥=|ΘW⊥|/TN≈12 implies a frustrated antiferromagnetism.
Graphical abstractSingle crystals of novel magnetoplumbite BaSn6Co6O19 have been characterized. .Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A novel compound magnetoplumbite BaSn6Co6O11 is synthesized in single crystalline form. ► It contains structural subunits with kagome topology, sandwiched between spinel blocks. ► Structural disorder in both subunits by random replacement of magnetic Co2+ with nonmagnetic Sn4+. ► Bulk magnetic measurements indicate long-range antiferromagnetic order below 14 K. ► The anisotropic frustration factor indicates strongly frustrated antiferromagnetism.
