| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1330549 | Journal of Solid State Chemistry | 2011 | 4 Pages |
A new borate, Cs2Al2B2O7, was synthesized by solid-state reaction. It crystallizes in the monoclinic space group P21/c with a=6.719(1) Å, b=7.121(1) Å, c=9.626(3) Å, β=115.3(1)°, and Z=2. In the structure, two AlO4 tetrahedra and two BO3 planar triangles are connected alternately by corner-sharing to from nearly planar [Al2B2O10] rings, which are further linked via common O1 atom to generate layers in the bc plane. These layers then share the O3 atoms lying on a center of inversion to form a three-dimensional framework with Cs atoms residing in the channels. The IR spectrum confirms the presence of both BO3 and AlO4 groups and the UV–vis–IR diffuse reflectance spectrum indicates a band gap of about 4.13(2) eV.
Graphical abstractA new borate, Cs2Al2B2O7, was synthesized. In the structure, BO3 triangles and AlO4 tetrahedra are connected to form a three-dimensional framework with Cs+ in the channels.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A new borate Cs2Al2B2O7 was synthesized and crystals were obtained by flux method. ► Cs2Al2B2O7 crystallizes in a new structure type. ► Two AlO4 and two BO3 generate a [Al2B2O10] ring in the structure. ► Rings are linked to form a three-dimensional framework with Cs+ in the channels. ► Optical band gap is about 4.13 eV.
