W18O49 nanorods decorated with Ag/AgCl nanoparticles as highly-sensitive gas-sensing material and visible-light-driven photocatalyst

A novel gas-sensing material and photocatalyst was successfully obtained by decorating Ag/AgCl nanoparticles on the W18O49 nanorods through a clean photochemical route. The as-prepared samples were characterized using combined techniques of X-ray diffractometry, electron microscopy, energy dispersive X-ray spectrometry, and X-ray photoelectron spectroscopy. Gas-sensing measurements indicate that the Ag/AgCl/W18O49 NRs sensors exhibit superior reducing gas-sensing properties to those of bare W18O49 NRs, and they are highly selective and sensitive to NH3, acetone, and H2S with short response and recovery times. The Ag/AgCl/W18O49 NRs photocatlysts also possess higher photocatalytic performance than bare W18O49 NRs for degradation of methyl orange under simulated sunlight irradiation. Possible mechanisms concerning the enhancement of gas-sensing and photocatalytic activities of the Ag/AgCl/W18O49 NRs composite were proposed.

Graphical AbstractThe Ag/AgCl nanoparticles adhered well to the W18O49 nanorod. The Ag could act as transfer center of the photoexcited carriers, prohibiting their recombinations in both W18O49 and AgCl.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Ag/AgCl/W18O49 NRs were successfully obtained via a clean photochemical route. ► The Ag/AgCl nanoparticles decorated on the W18O49 NRs possessed cladding structure. ► The Ag/AgCl/W18O49 NRs exhibited excellent gas-sensing and photocatalytic properties.