Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1330794 | Journal of Solid State Chemistry | 2010 | 5 Pages |
The physical properties including magnetic susceptibility, specific heat, and electrical resistivity of single crystals are reported for the compound CePd1+xAl6−x (x=0.5) which crystallizes in the tetragonal SrAu2Ga5-type structure (space group P4/mmm). The compound was grown from an excess of molten Al flux from the respective elements and the crystal structure was established from single-crystal X-ray diffraction. Anomalies in the low temperature specific heat Cp(T) and electrical resistivity ρ(T) show that the compound undergoes ferromagnetic order at TC=2.8 K. In the ordered state, CePd1.5Al5.5 displays heavy fermion behavior with a Sommerfeld coefficient of ca. 500 mJ/mol-K2.
Graphical abstractThe compound CePd1+xAl6-x (x=0.5) has been synthesized and structurally characterized by single-crystal X-ray diffraction. The measured physical properties of temperature and field dependent magnetic susceptibility, specific heat, and electrical resistivity suggests that the compound undergoes ferromagnetic order at ca. 2.8 K and further exhibits relatively heavy fermion behavior with a Sommerfeld coefficient of 500 mJ/mol-K2.Figure optionsDownload full-size imageDownload as PowerPoint slide