Article ID Journal Published Year Pages File Type
1330819 Journal of Solid State Chemistry 2011 5 Pages PDF
Abstract

The effect of CO2 on the two phase perovskite with average composition of BaCo0.4Fe0.4Zr0.2O3−δ is investigated by in-situ X-ray diffraction (XRD) as well as transmission electron microscopy (TEM). Partial decomposition of the BCFZ into high-temperature rhombohedral BaCO3 polymorph was observed during annealing in an atmosphere, which contained 50 vol% CO2/50 vol% N2 at 1173 K. This carbonate structure is not quenchable and cannot be detected by ex-situ methods. Additionally, the reversible phase transition of BaCO3 from orthorhombic to rhombohedral to cubic at different temperatures accompanied by formation of CoO was shown by in-situ XRD and TEM. Furthermore, complete regeneration of perovskite phase was obtained after high-temperature treatment under CO2-free conditions.

Graphical abstractIn-situ XRD of BCFZ powder in the atmosphere containing 50% CO2 and 50% N2 at different temperatures showing formation of BaCO3 and their phase transition.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Partial BCFZ decomposition. ► Rapid formation of rhombohedral BaCO3 after exposure of the CO2 at 1173 K. ► Reversible phase transition of BaCO3. ► Formation of CoO and tetragonal disordered Fe-enriched perovskite phase. ► Complete regeneration of BCFZ after removing of CO2.

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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