Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1330824 | Journal of Solid State Chemistry | 2011 | 9 Pages |
From literature data presently available, the decomposition temperature and the nature of the decomposition reaction of the ternary compound α-AlFeSi (also designated as αH or τ5) are not clearly identified. Moreover, some uncertainties remain concerning its crystal structure. The crystallographic structure and thermochemical behaviour of the ternary compound α-AlFeSi were meticulously studied. The crystal structure of α-AlFeSi was examined at room temperature from X-ray single crystal intensity data. It presents hexagonal symmetry, space group P63/mmc with unit cell parameters (293 K) a=12.345(2) Å and c=26.210(3) Å (V=3459 Å3). The average chemical formula obtained from refinement is Al7.1Fe2Si. From isothermal reaction-diffusion experiments and Differential Thermal Analysis, the title compound decomposes peritectically upon heating into θ-Fe4Al13(Si), γ-Al3FeSi and a ternary Al-rich liquid. Under atmospheric pressure, the temperature of this reversible transformation has been determined to be 772±12 °C.
Graphical abstractPartial representation of the crystal structure of the α-Al7.1Fe2Si compound.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlightsThe main findings of our work are: ► a detailed X-rays crystal structure determination of the ternary compound α-AlFeSi. ► The precision of the silicon atoms positions in the crystal structure. ► A precised determination of the decomposition temperature of this compound.