Hydrogenation of palladium rich compounds of aluminium, gallium and indium

Palladium rich intermetallic compounds of aluminium, gallium and indium have been studied before and after hydrogenation by powder X-ray diffraction and during hydrogenation by in situ thermal analysis (DSC) at hydrogen gas pressures up to 39 MPa and temperatures up to 700 K. Very weak DSC signals and small unit cell increases of below 1% for AlPd2, AlPd3, GaPd2, Ga5Pd13, In3Pd5, and InPd2 suggest negligible hydrogen uptake. In contrast, for both tetragonal modifications of InPd3 (ZrAl3 and TiAl3 type), heating to 523 K at 2 MPa hydrogen pressure leads to a rearrangement of the intermetallic structure to a cubic AuCu3 type with an increase in unit cell volume per formula unit by 3.6–3.9%. Gravimetric analysis suggests a composition InPd3H≈0.8 for the hydrogenation product. Very similar behaviour is found for the deuteration of InPd3.

Graphical abstractIn situ differential scanning calorimetry of the hydrogenation of tetragonal InPd3 (ZrAl3 type) at 1.3 MPa hydrogen pressure.Figure optionsDownload full-size imageDownload as PowerPoint slide