Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1330937 | Journal of Solid State Chemistry | 2009 | 6 Pages |
The thermoelectric properties of nominally undoped PbTe and Br doped PbTe materials sintered at high-pressure and high-temperature (HPHT) have been studied. All samples show n-type semiconducting behavior with negative thermopower. For undoped PbTe, four different HPHT treatments were performed at pressures between 4.0 and 6.5 GPa. PbTe doped with Br at 0.5, 1.0, 2.0, 3.0×1019 cm−3 was HPHT treated at 4.0 GPa and 1045 °C. As the dopant concentration increases, the absolute thermopower decreases, thermal conductivity increases, and electrical resistivity decreases. At a nominal dopant concentration of 1.0×1019 cm−3, carrier mobility of 1165 cm2/V s and dimensionless thermoelectric figure-of-merit, ZT, of around 0.27 at 300 K were obtained. These results demonstrate that HPHT post-processing is a viable and controllable way of tuning the thermoelectric properties of PbTe-based materials.
The effect, on thermoelectric properties, of sintering undoped and Br doped PbTe at pressures ≥4.0 GPa and 1045 °C are reported and compared with conventionally sintered materials.Figure optionsDownload full-size imageDownload as PowerPoint slide