| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1330938 | Journal of Solid State Chemistry | 2009 | 5 Pages |
Abstract
A [Ni(CN)4]2−-based two-dimensional Mn(II) coordination polymer {Mn(H2O)2[NiCN]4·4H2O}, in which the coordination layers are stacked on top of each other sandwiching 2D water layer of boat-shaped hexagonal water clusters has been synthesized. The complex exhibits high thermal decomposition temperature and reversible water absorption, which were clearly demonstrated by thermal and PXRD studies on the parent and rehydrated complex after dehydration.
A coordination polymer, {Mn(H2O)2[NiCN]4·4H2O}n, showed that the coordination layers are stacked on top of each other sandwiching 2D ice layer of boat-shaped hexagonal water clusters .Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ambarish Ray, Indrani Bhowmick, William S. Sheldrick, Atish Dipankar Jana, Mahammed Ali,