| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1331084 | Journal of Solid State Chemistry | 2010 | 6 Pages |
Abstract
Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group I41/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is non-bonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide.
Graphical AbstractA comparison of the central core in both compounds.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ehsan Jalilian, Sven Lidin,