| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1331110 | Journal of Solid State Chemistry | 2007 | 7 Pages |
57Fe Mössbauer spectroscopy, dc and ac magnetization, specific heat, and differential scanning calorimetry measurements were performed in a powder BiMn0.95Fe0.05O3 sample prepared at 6 GPa and 1383 K. The substitution of 5% Fe for Mn increases the temperatures of the structural monoclinic-to-orthorhombic phase transition (from 768 to 779 K) and the ferromagnetic transition (from 98 to 109 K) by about 10 K in BiMn0.95Fe0.05O3 compared with BiMnO3. On the other hand, the temperature of the monoclinic-to-monoclinic phase transition associated with the orbital ordering strongly decreases in BiMn0.95Fe0.05O3 (414 K) compared with that of BiMnO3 (474 K). The saturated magnetic moment at 5 K and 5 T is also suppressed from 3.92 μB per formula unit in BiMnO3 to 3.35 μB in BiMn0.95Fe0.05O3. The large quadrupole splitting (1.18 mm/s) observed at 293 K in BiMn0.95Fe0.05O3 can be explained by the strong Jahn-Teller distortion and cooperative orbital order. The quadrupole splitting reduces by two times above the orbital melting temperature.
Graphical abstractMössbauer spectra of BiMn0.95Fe0.05O3 at 523 and 293 K.Figure optionsDownload full-size imageDownload as PowerPoint slide
