| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1331131 | Journal of Solid State Chemistry | 2007 | 5 Pages |
Abstract
A manganese sulfite of the formula Mn5(OH)4(SO3)3·2H2O, I{a=7.5759(7) Å, b=8.4749(8) Å, c=10.852(1) Å, β=100.732(2)°, Z=2, space group=P21/m (no. 11), R1=0.0399 and wR2=0.1121 [for R indexes I>2σ(I)]}, comprising Mn3O14 units and extended Mn–O–Mn bonds along the three dimensions has been synthesized under hydrothermal conditions. It has narrow channels along the b-axis and exhibits hydrogen storage of 2.1 wt% at 300 K and 134 bar.
Graphical abstractA three-dimensional manganese sulfite with one-dimensional channels showing selective hydrogen absorption has been synthesized and characterized.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
K. Prabhakara Rao, A. Govindaraj, C.N.R. Rao,