| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1331230 | Journal of Solid State Chemistry | 2013 | 13 Pages |
A new willemite-type compound, [(Li, Na, H)0.16Zn1.92SiO4)] was synthesized from both solid-state reactions and molten NaCl. X-ray single crystal and neutron powder diffraction studies indicate the presence of Li+, Na+, and H+ in four and six membered-ring channels of alternately arranged ZnO4 and SiO4. The presence of channel cations is new to among numerous willemite-variants reported so far. This new configuration is attributed to defects at the Zn-sites. The new willemite-type material can be regarded as a prototype for combined cationic conductors.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A new willemite-type compound, (Li, Na, H)0.16Zn1.92SiO4 could be found for the first time. ► X-ray and neutron diffraction studies indicate the presence of Li+, Na+, and H+. ► The presence of these channel cations is attributed to 4% vacancy at Zn sites. ► This material can be regarded as a prototype for combined cationic conductors.
