| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1331508 | Journal of Solid State Chemistry | 2015 | 6 Pages |
•LSFCu was prepared by gel combustion route using EDTA and NH4NO3.•LSFCu shows a reversible phase transition at 425 °C from R-3c to Pm-3m phase.•The sample has a maximum conductivity value of 135 S cm−1 at 275 °C.•LSFCu shows a good chemical compatibility with CGO at 900 °C.
Nanocrystalline La0.6Sr0.4Fe0.8Cu0.2O3−δ (LSFCu) material was synthetized by combustion method using EDTA as fuel/chelating agent and NH4NO3 as combustion promoter. Structural characterization using thermodiffraction data allowed to determine a reversible phase transition at 425 °C from a low temperature R-3c phase to a high temperature Pm-3m phase and to calculate the thermal expansion coefficient (TEC) of both phases. Important characteristics for cathode application as electronic conductivity and chemical compatibility with Ce0.9Gd0.1O2−δ (CGO) electrolyte were evaluated. LSFCu presented a p-type conductor behavior with maximum conductivity of 135 S cm−1 at 275 °C and showed a good stability with CGO electrolyte at high temperatures. This work confirmed that as prepared LSFCu has excellent microstructural characteristics and an electrical conductivity between 100 and 60 S cm−1 in the 500–700 °C range which is sufficiently high to work as intermediate temperature Solid Oxide Fuel Cells (IT-SOFCs) cathode. However a change in the thermal expansion coefficient consistent with a small oxygen loss process may affect the electrode-electrolyte interface during fabrication and operation of a SOFC.
Graphical abstractNanocrystalline La0.6Sr0.4Fe0.8Cu0.2O3−δ was prepared by gel combustion and characterized by X-ray thermodiffraction and its conductivity was determined. The phase shows a reversible rhombohedral to cubic structural phase transition at 425 °C and a semiconductor to metallic phase transition at 275 °C.Figure optionsDownload full-size imageDownload as PowerPoint slide
