| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1331514 | Journal of Solid State Chemistry | 2015 | 5 Pages |
•New type of garnet vanadates Ca5M4V6O24 (M=Co, Ni) are synthesized by a high-temperature solid-state reaction.•Structural features are confirmed by single crystal samples.•Magnetic behaviors are firstly investigated in the systems.
Two vanadate compounds Ca5M4V6O24 (M=Co, Ni) have been synthesized by a high-temperature solid-state reaction. The compounds are found to crystallize in the cubic system with a space group Ia-3d, which exhibit a typical garnet structural framework. Magnetic measurements show that Ca5M4V6O24 (M=Co, Ni) exhibit similar magnetic behaviors, in which Ca5Co4V6O24 possesses an antiferromagnetic ordering at TN=~6 K while Ca5Ni4V6O24 shows an antiferromagnetic ordering at TN=~7 K.
Graphical abstractGarnet vanadate compounds Ca5M4V6O24 (M=Co, Ni) have been synthesized by a high-temperature solid-state reaction. Structural features and magnetic behaviors are also investigated.Figure optionsDownload full-size imageDownload as PowerPoint slide
