Synthesis and structure analysis of tetragonal Li7La3Zr2O12 with the garnet-related type structure

We have successfully synthesized a high-purity polycrystalline sample of tetragonal Li7La3Zr2O12. Single crystals have been also grown by a flux method. The single-crystal X-ray diffraction analysis verifies that tetragonal Li7La3Zr2O12 has the garnet-related type structure with a space group of I41/acd (no. 142). The lattice constants are a=13.134(4) Å and c=12.663(8) Å. The garnet-type framework structure is composed of two types of dodecahedral LaO8 and octahedral ZrO6. Li atoms occupy three crystallographic sites in the interstices of this framework structure, where Li(1), Li(2), and Li(3) atoms are located at the tetrahedral 8a site and the distorted octahedral 16f and 32g sites, respectively. The structure is also investigated by the Rietveld method with X-ray and neutron powder diffraction data. These diffraction patterns are identified as the tetragonal Li7La3Zr2O12 structure determined from the single-crystal data. The present tetragonal Li7La3Zr2O12 sample exhibits a bulk Li-ion conductivity of σb=1.63×10−6 S cm−1 and grain-boundary Li-ion conductivity of σgb=5.59×10−7 S cm−1 at 300 K. The activation energy is estimated to be Ea=0.54 eV in the temperature range of 300–560 K.

Graphical abstractGarnet-related Li7La3Zr2O12 having tetragonal symmetry (I41/acd, no.142) has been successfully synthesized. Single crystals have been also grown by a flux method. The single-crystal X-ray diffraction analysis verifies that tetragonal Li7La3Zr2O12 has the garnet-related type structure with the lattice constants of a=13.134(4) Å and c=12.663(8) Å and the fully ordered arrangement of Li atoms.Figure optionsDownload full-size imageDownload as PowerPoint slide