Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1331748 | Journal of Solid State Chemistry | 2006 | 7 Pages |
The single crystals of caesium magnesium titanium (IV) tri-oxo-tetrakis-diphosphate bis-monophosphate, Cs3.70Mg0.60Ti2.78(TiO)3(P2O7)4(PO4)2, crystallize in sp. gr. P-1 (No. 2) with cell parameters a=6.3245(4), b=9.5470(4), c=15.1892(9) Å, α=72.760(4), β=85.689(5), γ=73.717(4), z=1. The titled compound possesses a three-dimensional tunnel structure built by the corner-sharing of distorted [TiO6] octahedra, [Ti2O11] bioctahedra, [PO4] monophosphate and [P2O7] pyrophosphate groups. The Cs+ cations are located in the tunnels. The partial substitution of Ti positions with Mg atoms is observed. The negative charge of the framework is balanced by Cs cations and Mg atoms leading to pronounced concurrency and orientation disorder in the [P2O7] groups, which coordinate both.
Graphical abstractProjection of Cs3.70Mg0.60Ti2.78(TiO)3(P2O7)4(PO4)2 on the bc plane.Figure optionsDownload full-size imageDownload as PowerPoint slide